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NEET CHEMISTRYCoordination CompoundsMedium

Question

The sum of coordination number and oxidation number of the metal M in the complex [M(en)2(C2O4)]Cl[M(en)_2(C_2O_4)]Cl (where, en is ethylenediamine) is:

A

9

B

6

C

7

D

8

Step-by-Step Solution

In the complex [M(en)2(C2O4)]Cl[M(en)_2(C_2O_4)]Cl:

  1. Coordination Number (CN): The ligands are ethylenediamine (enen), which is a neutral didentate ligand, and oxalate (C2O42C_2O_4^{2-}), which is an anionic didentate ligand. Total number of donor atoms bound to the metal M=(2×2)+(1×2)=6M = (2 \times 2) + (1 \times 2) = 6. Therefore, the coordination number is 6.
  2. Oxidation Number (ON): Let the oxidation state of metal M be xx. The overall charge on the complex cation [M(en)2(C2O4)]+[M(en)_2(C_2O_4)]^+ is +1+1 (to balance the ClCl^- counter ion). So, x+2(0)+1(2)=+1x2=+1x=+3x + 2(0) + 1(-2) = +1 \Rightarrow x - 2 = +1 \Rightarrow x = +3. The oxidation number is 3.

The sum of the coordination number and oxidation number is 6+3=96 + 3 = 9.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundscoordinationnumberoxidationnumbercomplex

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