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NEET CHEMISTRYChemical Bonding and Molecular StructureEasy

Question

Which among the following species has a triangular planar shape?

A

N3\text{N}_3^-

B

NO3\text{NO}_3^-

C

NO2\text{NO}_2^-

D

CO2\text{CO}_2

Step-by-Step Solution

To find the shape of the given species, we can determine the steric number (number of σ\sigma bonds + number of lone pairs on the central atom) according to VSEPR theory:

  • NO3\text{NO}_3^- (Nitrate ion): The central nitrogen atom forms 33 σ\sigma bonds with three oxygen atoms and has 00 lone pairs. The steric number is 33, which corresponds to sp2sp^2 hybridisation and a trigonal planar (or triangular planar) geometry.
  • N3\text{N}_3^- (Azide ion): The central nitrogen atom forms 22 σ\sigma bonds with the terminal nitrogen atoms and has 00 lone pairs. The steric number is 22, which gives it a linear shape.
  • NO2\text{NO}_2^- (Nitrite ion): The central nitrogen atom forms 22 σ\sigma bonds and possesses 11 lone pair. The steric number is 33, but due to the presence of a lone pair, its shape is bent or V-shaped.
  • CO2\text{CO}_2 (Carbon dioxide): The central carbon atom forms 22 σ\sigma bonds (double bonds) with oxygen atoms and has 00 lone pairs. The steric number is 22, giving it a linear shape.

Therefore, NO3\text{NO}_3^- is the species with a triangular planar shape.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Chemical Bonding and Molecular Structure. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYChemical Bonding and Molecular Structurefollowingspeciestriangularplanar

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