A pair of enantiomorphs (optical isomers) exists for chiral complexes that are non-superimposable on their mirror images. This requires the absence of a plane of symmetry.
(A) [Co(NH3)4Cl2]+, an [Ma4b2] type complex, exhibits geometrical isomerism (cis and trans). Both isomers possess a plane of symmetry and are optically inactive.
(B) [Cr(NH3)6][Co(CN)6] consists of highly symmetrical [Ma6] type complex ions, neither of which shows optical isomerism.
(C) [Co(en)2Cl2]+, an [M(AA)2b2] type complex, exists in cis and trans forms. The trans-isomer has a plane of symmetry and is optically inactive. The cis-isomer, however, lacks a plane of symmetry and is optically active, existing as a pair of enantiomers (dextro and laevo).
(D) [Pt(NH3)4][PtCl6] contains a square planar cation and an octahedral anion, both of which are highly symmetrical and optically inactive.