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NEET CHEMISTRYClassification of Elements and Periodicity in PropertiesMedium

Question

For the second-period elements, the correct increasing order of first ionisation enthalpy is:

A

Li < Be < B < C < O < N < F < Ne

B

Li < Be < B < C < N < O < F < Ne

C

Li < B < Be < C < O < N < F < Ne

D

Li < B < Be < C < N < O < F < Ne

Step-by-Step Solution

Generally, ionization enthalpy increases across a period from left to right due to increased nuclear charge and smaller atomic radius. However, there are two anomalies in the second period:

  1. Boron (B) < Beryllium (Be): Beryllium has a stable full-filled electronic configuration (1s22s21s^2 2s^2), while Boron (1s22s22p11s^2 2s^2 2p^1) has a single electron in the 2p orbital. It is easier to remove the 2p electron from Boron because it is less penetrating towards the nucleus and more shielded by the inner core than the 2s electrons of Beryllium .
  2. Oxygen (O) < Nitrogen (N): Nitrogen (1s22s22p31s^2 2s^2 2p^3) has a stable half-filled p-orbital configuration. In Oxygen (1s22s22p41s^2 2s^2 2p^4), two of the four 2p electrons occupy the same orbital, resulting in increased electron-electron repulsion. Consequently, it is easier to remove an electron from Oxygen than from the stable Nitrogen configuration .

Thus, the correct order is Li < B < Be < C < O < N < F < Ne.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Classification of Elements and Periodicity in Properties. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYClassification of Elements and Periodicity in Propertiessecondperiodelementscorrectincreasingionisation

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