Question
The correct 'spin only' magnetic moments of and respectively, are:
0 BM and 4.9 BM
0 BM and 0 BM
4.9 BM and 0 BM
4.9 BM and 4.9 BM
In , the central metal ion Co is in the +3 oxidation state, which has a electronic configuration. Since is a weak field ligand, the crystal field splitting energy is less than the pairing energy (). Thus, it forms a high-spin complex with the configuration . It has 4 unpaired electrons (). The spin-only magnetic moment is BM.
In , Co is also in the +3 oxidation state (). However, the oxalate ligand (), being a chelating ligand, acts as a strong field ligand when complexed with . This causes the electrons to pair up (), resulting in a low-spin complex with the configuration . It has 0 unpaired electrons (), meaning it is diamagnetic with a magnetic moment of 0 BM.
This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.
More Coordination Compounds Questions
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