Question
The crystal field stabilization energy (CFSE) for is . The CFSE for will be:
6000 cm⁻¹
16000 cm⁻¹
18000 cm⁻¹
8000 cm⁻¹
The problem asks for the crystal field splitting energy of a tetrahedral complex () given the splitting energy of the corresponding octahedral complex (). According to Crystal Field Theory, for the same metal, the same ligands, and similar metal-ligand distances, the relationship between the tetrahedral splitting energy () and the octahedral splitting energy () is given by the equation:
Given that for , we can calculate for :
(Note: While the question uses the term 'CFSE', in this context it refers to the magnitude of the crystal field splitting parameter, ).
This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.
More Coordination Compounds Questions
The complex, $[\text{Pt}(\text{Py})(\text{NH}_3)\text{BrCl}]$ will have how many geometrical isomers?
Among the given complexes, the complex having the highest paramagnetic behaviour is: (At. No. Ti = 22, Cr = 24, Co = 27, Zn = 30)
Mg is present in:
The complexes $[\text{Co}(\text{NH}_3)_6][\text{Cr}(\text{CN})_6]$ and $[\text{Cr}(\text{NH}_3)_6][\text{Co}(\text{CN})_6]$ are examples of:
The coordination compound that gives the maximum number of isomers is:
$[Cu(NH_3)_4]^{2+}$ reacts with $HNO_3$ in excess of water and gives:
CFSE (in the octahedral field) will be maximum in: (Atomic number Co = 27)
The IUPAC name of the following complex is: $[Ag(H_2O)_2][Ag(CN)_2]$
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