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NEET CHEMISTRYCoordination CompoundsEasy

Question

The crystal field stabilization energy (CFSE) for [CoCl6]4[CoCl_6]^{4-} is 18000 cm118000 \text{ cm}^{-1}. The CFSE for [CoCl4]2[CoCl_4]^{2-} will be:

A

6000 cm⁻¹

B

16000 cm⁻¹

C

18000 cm⁻¹

D

8000 cm⁻¹

Step-by-Step Solution

The problem asks for the crystal field splitting energy of a tetrahedral complex (Δt\Delta_t) given the splitting energy of the corresponding octahedral complex (Δo\Delta_o). According to Crystal Field Theory, for the same metal, the same ligands, and similar metal-ligand distances, the relationship between the tetrahedral splitting energy (Δt\Delta_t) and the octahedral splitting energy (Δo\Delta_o) is given by the equation:

Δt=49Δo\Delta_t = \frac{4}{9} \Delta_o

Given that Δo=18000 cm1\Delta_o = 18000 \text{ cm}^{-1} for [CoCl6]4[CoCl_6]^{4-}, we can calculate Δt\Delta_t for [CoCl4]2[CoCl_4]^{2-}:

Δt=49×18000 cm1\Delta_t = \frac{4}{9} \times 18000 \text{ cm}^{-1} Δt=4×2000 cm1\Delta_t = 4 \times 2000 \text{ cm}^{-1} Δt=8000 cm1\Delta_t = 8000 \text{ cm}^{-1}

(Note: While the question uses the term 'CFSE', in this context it refers to the magnitude of the crystal field splitting parameter, Δ\Delta).

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundscrystalstabilizationenergy

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