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NEET CHEMISTRYCoordination CompoundsMedium

Question

The order of energy absorbed, which is responsible for the color of complexes, is: (A) [Ni(H2O)2(en)2]2+[Ni(H_2O)_2(en)_2]^{2+} (B) [Ni(H2O)4(en)]2+[Ni(H_2O)_4(en)]^{2+} (C) [Ni(en)3]2+[Ni(en)_3]^{2+}

A

B > A > C

B

A > B > C

C

C > B > A

D

C > A > B

Step-by-Step Solution

The energy of light absorbed by a coordination complex is directly proportional to its crystal field splitting energy (Δo\Delta_o), which in turn depends on the field strength of the ligands present. According to the spectrochemical series, ethylenediamine (enen) is a stronger field ligand than water (H2OH_2O). As the number of enen ligands replacing H2OH_2O increases, the magnitude of Δo\Delta_o increases, leading to the absorption of light of higher energy (shorter wavelength). The number of enen ligands in the given complexes is: (C) [Ni(en)3]2+[Ni(en)_3]^{2+} : 3 enen ligands (Maximum Δo\Delta_o) (A) [Ni(H2O)2(en)2]2+[Ni(H_2O)_2(en)_2]^{2+} : 2 enen ligands (B) [Ni(H2O)4(en)]2+[Ni(H_2O)_4(en)]^{2+} : 1 enen ligand (Minimum Δo\Delta_o) Therefore, the correct order of energy absorbed is C > A > B.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundsenergyabsorbedresponsiblecomplexesnihoen

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