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CHEMISTRYChemical Bonding and Molecular StructureMedium

Which of the following pairs of ions are isoelectronic and isostructural?

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CHEMISTRYCoordination CompoundsEasy

An example of a sigma bonded organometallic compound is:

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PHYSICSMedium

Find the value of the angle of emergence from the prism. Refractive index of the glass is $\sqrt{3}$.

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CHEMISTRYCoordination CompoundsMedium

Type of isomerism exhibited by compounds $[Cr(H_2O)_6]Cl_3$, $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$, $[Cr(H_2O)_4Cl_2]Cl \cdot 2H_2O$ and the value of coordination number (CN) of central metal ion in all these compounds, respectively, is:

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CHEMISTRYCoordination CompoundsMedium

Select the correct option based on the statements below: **Assertion (A):** The metal-carbon bond in metal carbonyls possesses both $\sigma$ and $\pi$ character. **Reason (R):** The ligand to metal bond is a $\pi$ bond and metal to ligand bond is a $\sigma$ bond.

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CHEMISTRYChemical Bonding and Molecular StructureMedium

Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them.

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CHEMISTRYChemical Bonding and Molecular StructureMedium

A species that does not exhibit paramagnetism is:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

The correct shape and hybridisation of BrF$_5$ is:

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CHEMISTRYCoordination CompoundsMedium

Which of the following has the longest C—O bond length? (Free C—O bond length in CO is 1.128 Å)

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CHEMISTRYCoordination CompoundsEasy

Homoleptic complex from the following complexes is:

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CHEMISTRYCoordination CompoundsMedium

Which of the following has the longest C-O bond length? (Free C-O bond length in CO is 1.128 Å.)

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CHEMISTRYChemical Bonding and Molecular StructureMedium

The correct order of C-O bond length among CO, $CO_3^{2-}$, and $CO_2$ is:

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CHEMISTRYCoordination CompoundsMedium

A low spin complex of $d^6$-cation in an octahedral field will have the following energy: ($\Delta_0$ = Crystal field splitting energy in an octahedral field, $P$ = Electron pairing energy)

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CHEMISTRYMedium

BF_{3} is planar and electron deficient compound. Hybridization and number of electrons around the central atom, respectively are :

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CHEMISTRYCoordination CompoundsMedium

The sum of coordination number and oxidation number of the metal M in the complex $[M(en)_2(C_2O_4)]Cl$ (where, en is ethylenediamine) is:

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CHEMISTRYCoordination CompoundsMedium

A red precipitate is obtained when an ethanol solution of dimethylglyoxime is added to ammoniacal Ni(II). Which of the following statements is not true?

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CHEMISTRYCoordination CompoundsMedium

The correct order of spin-only magnetic moment for the given complexes is:

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CHEMISTRYChemical Bonding and Molecular StructureMedium

A diatomic molecule, among the following species, that only has $\pi$ bonds according to the Molecular Orbital Theory (MOT) is:

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BIOLOGYMedium

It takes very long time for pineapple plants to produce flowers. Which combination of hormones can be applied to artificially induce flowering in pineapple plants throughout the year to increase yield?

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CHEMISTRYHydrocarbonsMedium

Predict the correct intermediate and product in the following reaction: $$ H_3C-C \equiv CH \xrightarrow{H_2O, H_2SO_4, HgSO_4} \text{Intermediate} \to \text{Product} $$

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