Question
Select the correct option based on the statements below: Assertion (A): The metal-carbon bond in metal carbonyls possesses both and character. Reason (R): The ligand to metal bond is a bond and metal to ligand bond is a bond.
Both (A) and (R) are True and (R) is the correct explanation of (A).
Both (A) and (R) are True but (R) is not the correct explanation of (A).
(A) is True but (R) is False.
(A) is False but (R) is True.
Assertion (A) is true because the metal-carbon bond in metal carbonyls possesses both and character. Reason (R) is false because the ligand to metal bond is a bond (formed by the donation of a lone pair of electrons on the carbonyl carbon into a vacant orbital of the metal) and the metal to ligand bond is a bond (formed by the donation of a pair of electrons from a filled orbital of the metal into the vacant antibonding orbital of carbon monoxide).
This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.
More Coordination Compounds Questions
The complex, $[\text{Pt}(\text{Py})(\text{NH}_3)\text{BrCl}]$ will have how many geometrical isomers?
Among the given complexes, the complex having the highest paramagnetic behaviour is: (At. No. Ti = 22, Cr = 24, Co = 27, Zn = 30)
Mg is present in:
The complexes $[\text{Co}(\text{NH}_3)_6][\text{Cr}(\text{CN})_6]$ and $[\text{Cr}(\text{NH}_3)_6][\text{Co}(\text{CN})_6]$ are examples of:
The coordination compound that gives the maximum number of isomers is:
$[Cu(NH_3)_4]^{2+}$ reacts with $HNO_3$ in excess of water and gives:
CFSE (in the octahedral field) will be maximum in: (Atomic number Co = 27)
The IUPAC name of the following complex is: $[Ag(H_2O)_2][Ag(CN)_2]$
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