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NEET CHEMISTRYCoordination CompoundsMedium

Question

Match the complex ions in List-I with their corresponding hybridization in List-II.

List-I (Complex ion) (A) [Ni(CN)4]2[Ni(CN)_4]^{2-} (B) [CoF6]3[CoF_6]^{3-} (C) [Co(C2O4)3]3[Co(C_2O_4)_3]^{3-} (D) [NiCl4]2[NiCl_4]^{2-}

List-II (Hybridisation) (I) sp3sp^3 (II) d2sp3d^2sp^3 (III) sp3d2sp^3d^2 (IV) dsp2dsp^2

Choose the correct answer from the options given below:

A

(A)-(IV), (B)-(III), (C)-(II), (D)-(I)

B

(A)-(III), (B)-(I), (C)-(IV), (D)-(II)

C

(A)-(I), (B)-(II), (C)-(III), (D)-(IV)

D

(A)-(III), (B)-(IV), (C)-(II), (D)-(I)

Step-by-Step Solution

According to Valence Bond Theory : (A) [Ni(CN)4]2[Ni(CN)_4]^{2-}: The central metal ion is Ni2+Ni^{2+} with a 3d83d^8 configuration. CNCN^- is a strong field ligand, causing the pairing of unpaired dd electrons. This vacates one 3d3d orbital. The hybridization is dsp2dsp^2 forming a square planar complex . (B) [CoF6]3[CoF_6]^{3-}: The central metal ion is Co3+Co^{3+} with a 3d63d^6 configuration. FF^- is a weak field ligand, so no pairing of dd electrons occurs. It uses outer 4d4d orbitals for hybridization, which is sp3d2sp^3d^2 (outer orbital octahedral complex) . (C) [Co(C2O4)3]3[Co(C_2O_4)_3]^{3-}: The central metal ion is Co3+Co^{3+} (3d63d^6). The oxalate ion (C2O42C_2O_4^{2-}) acts as a strong field ligand for Co3+Co^{3+} causing pairing of electrons. It uses inner 3d3d orbitals for hybridization, which is d2sp3d^2sp^3 (inner orbital octahedral complex) . (D) [NiCl4]2[NiCl_4]^{2-}: The central metal ion is Ni2+Ni^{2+} (3d83d^8). ClCl^- is a weak field ligand, so no pairing occurs. The hybridization involves one 4s4s and three 4p4p orbitals, resulting in sp3sp^3 hybridization (tetrahedral complex) . Therefore, the correct matching is A-IV, B-III, C-II, D-I.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundscomplexcorrespondinghybridizationlistiicomplex

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