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NEET CHEMISTRYCoordination CompoundsMedium

Question

The correct increasing order of trans-effect of the following species is:

A

NH₃ > CN⁻ > Br⁻ > C₆H₅⁻

B

CN⁻ > C₆H₅⁻ > Br⁻ > NH₃

C

Br⁻ > CN⁻ > NH₃ > C₆H₅⁻

D

CN⁻ > Br⁻ > C₆H₅⁻ > NH₃

Step-by-Step Solution

The trans-effect is the ability of a coordinated ligand to direct the substitution of the ligand occupying the position trans (opposite) to itself. The intensity of the trans-effect follows an empirical series.

  1. General Order: Strong π\pi-acceptors > Strong σ\sigma-donors > Weak π\pi-donors/Weak σ\sigma-donors.
  2. Specific Ligands:
  • CNCN^- (Cyanide): A very strong trans-directing ligand due to strong σ\sigma-bonding and π\pi-backbonding capabilities. It is at the high end of the series.
  • C6H5C_6H_5^- (Phenyl): A strong σ\sigma-donor ligand, typically placed higher than halides but lower than cyanide.
  • BrBr^- (Bromide): A halide, acts as a weak to moderate trans-director. Its effect is less than that of CNCN^- or C6H5C_6H_5^- but greater than neutral amines.
  • NH3NH_3 (Ammonia): A neutral ligand with no π\pi-bonding capability, acting as a relatively weak trans-director.
  1. Conclusion: The decreasing order of trans-effect is: CN>C6H5>Br>NH3CN^- > C_6H_5^- > Br^- > NH_3. (Note: Although the question asks for 'increasing' order, the options use the '>' symbol, indicating a decreasing sequence from left to right, which matches the standard series).

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundscorrectincreasingtranseffectfollowingspecies

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