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NEET CHEMISTRYCoordination CompoundsMedium

Question

The number of possible isomers for the complex [Co(en)2Cl2]Cl[Co(en)_2Cl_2]Cl will be (en = ethylenediamine):

A

2

B

1

C

3

D

4

Step-by-Step Solution

The complex [Co(en)2Cl2]Cl[Co(en)_2Cl_2]Cl ionizes to give the coordination entity [Co(en)2Cl2]+[Co(en)_2Cl_2]^+. This complex belongs to the type [M(AA)2a2][M(AA)_2a_2], where 'AA' is a symmetrical bidentate ligand (enen) and 'a' is a monodentate ligand (ClCl^-).

  1. Geometrical Isomerism: The complex shows geometrical isomerism with two forms:
  • Trans-isomer: The two ClCl^- ions are at 180° to each other. This structure has a plane of symmetry and is optically inactive (achiral).
  • Cis-isomer: The two ClCl^- ions are at 90° to each other. This structure lacks a plane of symmetry and is optically active.
  1. Optical Isomerism:
  • The cis-isomer is chiral and exists as a pair of enantiomers (dextro and laevo forms).
  • The trans-isomer is achiral and does not show optical isomerism.

Total Isomers: 1 (Trans) + 2 (Cis-d and Cis-l) = 3 isomers .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundsnumberpossibleisomerscomplexcoenclcl

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