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NEET CHEMISTRYCoordination CompoundsMedium

Question

The type of isomerism shown by the complex [CoCl2(en)2]+ is:

A

Geometrical isomerism

B

Coordination isomerism

C

Ionization isomerism

D

Linkage isomerism

Step-by-Step Solution

The complex ion [CoCl2(en)2]+[CoCl_2(en)_2]^+ represents an octahedral complex of the type [M(AA)2a2][M(AA)_2a_2], where 'AA' is the symmetrical bidentate ligand ethane-1,2-diamine (enen) and 'a' is the monodentate ligand chloride (ClCl^-).

This specific type of complex exhibits Geometrical Isomerism consisting of two isomers :

  1. Cis-isomer: The two chloride ions occupy adjacent positions (90°) relative to each other.
  2. Trans-isomer: The two chloride ions occupy positions opposite to each other (180°).

Analysis of other options:

  • Linkage isomerism requires ambidentate ligands (like NO2NO_2 or SCNSCN), which are not present here .
  • Coordination isomerism occurs when both the cation and anion are complex ions, which is not the case .
  • Ionization isomerism would require the exchange of a ligand with a counter ion outside the coordination sphere. Since only the complex ion is specified without a specific counter ion capable of exchange, this is not the primary isomerism defined for the ion itself .

Therefore, Geometrical isomerism is the correct answer.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundsisomerismcomplexcoclen

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